Will The Ubuntu 12.04 version of Puppet Enterprise work with Ubuntu 12.10?

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Only LTS releases are supported by Puppet Enterprise. You might be able to hack it into working, but then you'll compromise your ability to get support from Puppetlabs.

You could point the matching version of Puppet OSS at your master, but again, you're off the rails, and your mileage may vary.

From my experience there were no big changes with 12.10 that could effect a Puppet installation. Although I use to stick with the LTS versions of Ubuntu. In the past I had a lot of trouble with the version of Ubuntu which came after the LTS Version a.k.a. 10.10 was crap! ;-)

But if you need to install it, give it a try. :-)